============================================================================= SHIFTS, version 4.1 [X.-P. Xu and D.A. Case, Mar. 2002] ============================================================================= shifts will be computed for atoms matching ::H* found 6 rings ring int. center anis. iso. TYR 13 0.840 -6.461 -1.833 -0.460 -99.200 -91.000 PHE 22 1.000 -0.215 -1.729 5.601 -99.200 -91.000 HIS 24 0.900 -10.099 2.266 2.817 -99.200 -91.000 HIS 25 0.900 -7.607 4.242 -0.091 -99.200 -91.000 HIS 31 0.900 4.224 0.965 5.156 -99.200 -91.000 HIS 35 0.900 8.961 1.269 2.947 -99.200 -91.000 ============================================================================= Atom RingCur El P_anis Const RC pred Obs ============================================================================= 2enhA14 GLY 1 HA2 -0.00 -0.12 0.18 -0.51 4.01 3.56 2enhA14 GLY 1 HA3 -0.00 0.02 0.16 -0.51 4.01 3.67 2enhA14 SER 2 H -0.00 0.09 0.06 -0.55 8.46 8.07 2enhA14 SER 2 HA -0.00 0.14 0.30 -0.75 4.49 4.17 2enhA14 SER 2 HB2 -0.00 0.07 0.08 -0.04 3.95 4.06 2enhA14 SER 2 HB3 -0.00 -0.12 0.12 -0.04 3.93 3.89 2enhA14 SER 3 H -0.00 0.00 -0.19 -0.55 8.46 7.73 2enhA14 SER 3 HA -0.00 -0.05 0.26 -0.75 4.49 3.94 2enhA14 SER 3 HB2 -0.00 -0.04 -0.13 -0.04 3.95 3.74 2enhA14 SER 3 HB3 -0.00 0.23 -0.12 -0.04 3.93 4.00 2enhA14 GLY 4 H -0.00 -0.18 -0.35 -0.55 8.43 7.35 2enhA14 GLY 4 HA2 -0.00 -0.00 0.23 -0.51 4.01 3.73 2enhA14 GLY 4 HA3 -0.00 0.25 0.67 -0.51 4.01 4.42 2enhA14 SER 5 H -0.00 -0.06 0.10 -0.55 8.46 7.96 2enhA14 SER 5 HA -0.00 0.22 0.65 -0.75 4.49 4.60 2enhA14 SER 5 HB2 -0.00 -0.04 0.07 -0.04 3.95 3.93 2enhA14 SER 5 HB3 -0.00 -0.07 0.13 -0.04 3.93 3.95 2enhA14 SER 6 H -0.00 -0.07 0.07 -0.55 8.46 7.92 2enhA14 SER 6 HA -0.00 0.13 0.65 -0.75 4.49 4.52 2enhA14 SER 6 HB2 -0.00 0.01 0.02 -0.04 3.95 3.94 2enhA14 SER 6 HB3 -0.00 -0.01 0.06 -0.04 3.93 3.94 2enhA14 GLY 7 H -0.00 0.08 0.09 -0.55 8.43 8.06 2enhA14 GLY 7 HA2 -0.00 -0.05 0.33 -0.51 4.01 3.77 2enhA14 GLY 7 HA3 -0.00 0.26 0.80 -0.51 4.01 4.56 2enhA14 THR 8 H -0.00 0.17 0.09 -0.55 8.28 7.99 2enhA14 THR 8 HA -0.00 0.20 0.94 -0.75 4.39 4.77 2enhA14 THR 8 HB -0.00 -0.01 0.15 -0.04 4.32 4.42 2enhA14 THR 8 HG23 0.00 0.01 -0.06 -0.04 1.22 1.13 2enhA14 GLY 9 H -0.00 0.21 -0.06 -0.55 8.43 8.03 2enhA14 GLY 9 HA2 0.00 0.01 0.36 -0.51 4.01 3.87 2enhA14 GLY 9 HA3 -0.01 0.08 0.41 -0.51 4.01 3.99 2enhA14 GLU 10 H 0.01 0.19 0.07 -0.55 8.60 8.32 2enhA14 GLU 10 HA 0.01 0.15 0.77 -0.75 4.29 4.47 2enhA14 GLU 10 HB2 0.00 0.08 -0.16 -0.04 2.09 1.97 2enhA14 GLU 10 HB3 0.01 -0.05 0.08 -0.04 1.99 1.99 2enhA14 GLU 10 HG2 0.00 -0.01 -0.28 -0.04 2.34 2.02 2enhA14 GLU 10 HG3 0.00 0.05 0.02 -0.04 2.34 2.37 2enhA14 LYS 11 H 0.03 0.22 0.17 -0.55 8.42 8.29 2enhA14 LYS 11 HA 0.06 0.22 1.01 -0.75 4.32 4.85 2enhA14 LYS 11 HB2 0.12 -0.01 0.19 -0.04 1.87 2.12 2enhA14 LYS 11 HB3 0.23 -0.08 0.17 -0.04 1.79 2.07 2enhA14 LYS 11 HG2 0.14 0.16 0.21 -0.04 1.46 1.94 2enhA14 LYS 11 HG3 0.11 0.00 0.11 -0.04 1.46 1.64 2enhA14 LYS 11 HD2 0.05 -0.02 -0.14 -0.04 1.69 1.54 2enhA14 LYS 11 HD3 0.04 -0.26 -0.67 -0.04 1.68 0.75 2enhA14 LYS 11 HE2 0.01 -0.04 -0.18 -0.04 2.99 2.73 2enhA14 LYS 11 HE3 0.04 0.02 -0.12 -0.04 2.99 2.89 2enhA14 PRO 12 HA -0.12 0.11 0.38 -0.51 4.44 4.30 2enhA14 PRO 12 HB2 -0.52 -0.01 0.09 -0.04 2.28 1.80 2enhA14 PRO 12 HB3 -0.16 0.03 0.12 -0.04 2.02 1.97 2enhA14 PRO 12 HG2 -0.37 0.02 -0.00 -0.04 2.03 1.64 2enhA14 PRO 12 HG3 -0.05 0.03 0.09 -0.04 2.03 2.05 2enhA14 PRO 12 HD2 0.15 0.16 0.27 -0.04 3.68 4.22 2enhA14 PRO 12 HD3 0.02 0.16 0.22 -0.04 3.65 4.01 2enhA14 TYR 13 H 0.13 0.06 -0.80 -0.55 8.29 7.13 2enhA14 TYR 13 HA 0.06 0.18 0.91 -0.75 4.56 4.96 2enhA14 TYR 13 HB2 0.15 0.01 -0.13 -0.04 3.06 3.04 2enhA14 TYR 13 HB3 0.09 -0.05 -0.07 -0.04 2.98 2.90 2enhA14 TYR 13 HD2 0.07 0.08 -0.12 -0.04 7.15 7.13 2enhA14 TYR 13 HE2 0.06 0.04 -0.02 -0.04 6.85 6.89 2enhA14 GLU 14 H 0.18 0.23 0.12 -0.55 8.60 8.58 2enhA14 GLU 14 HA 0.23 0.34 0.64 -0.75 4.29 4.75 2enhA14 GLU 14 HB2 0.08 0.14 -0.34 -0.04 2.09 1.93 2enhA14 GLU 14 HB3 0.07 -0.03 -0.15 -0.04 1.99 1.84 2enhA14 GLU 14 HG2 0.07 -0.07 -0.16 -0.04 2.34 2.14 2enhA14 GLU 14 HG3 0.04 0.03 -0.24 -0.04 2.34 2.14 2enhA14 CYS 15 H 0.20 0.45 0.25 -0.55 8.50 8.86 2enhA14 CYS 15 HA 0.15 0.16 0.70 -0.75 4.58 4.84 2enhA14 CYS 15 HB2 0.25 0.16 0.17 -0.04 2.97 3.51 2enhA14 CYS 15 HB3 0.19 -0.30 0.26 -0.04 2.97 3.08 2enhA14 ASP 16 H 0.08 0.24 0.20 -0.55 8.40 8.37 2enhA14 ASP 16 HA 0.03 0.18 0.52 -0.75 4.63 4.60 2enhA14 ASP 16 HB2 0.04 0.04 0.11 -0.04 2.71 2.86 2enhA14 ASP 16 HB3 0.02 0.01 0.10 -0.04 2.70 2.79 2enhA14 VAL 17 H 0.05 -0.21 -0.79 -0.55 8.24 6.74 2enhA14 VAL 17 HA -0.07 0.30 0.93 -0.75 4.13 4.53 2enhA14 VAL 17 HB -0.31 -0.12 0.05 -0.04 2.12 1.69 2enhA14 VAL 17 HG13 -0.53 0.03 -0.11 -0.04 0.97 0.32 2enhA14 VAL 17 HG23 -0.10 0.00 -0.19 -0.04 0.95 0.62 2enhA14 CYS 18 H 0.08 -0.12 0.06 -0.55 8.50 7.98 2enhA14 CYS 18 HA 0.03 0.30 0.86 -0.75 4.58 5.02 2enhA14 CYS 18 HB2 0.12 0.06 0.06 -0.04 2.97 3.18 2enhA14 CYS 18 HB3 0.18 0.05 -0.05 -0.04 2.97 3.11 2enhA14 ARG 19 H 0.06 -0.02 0.02 -0.55 8.46 7.97 2enhA14 ARG 19 HA 0.04 0.21 0.38 -0.75 4.34 4.22 2enhA14 ARG 19 HB2 0.01 0.24 -0.08 -0.04 1.90 2.02 2enhA14 ARG 19 HB3 0.01 -0.02 0.19 -0.04 1.80 1.93 2enhA14 ARG 19 HG2 0.01 0.01 -0.07 -0.04 1.67 1.57 2enhA14 ARG 19 HG3 0.02 0.03 -0.04 -0.04 1.67 1.63 2enhA14 ARG 19 HD2 0.01 0.03 -0.25 -0.04 3.22 2.97 2enhA14 ARG 19 HD3 0.02 -0.26 -0.72 -0.04 3.22 2.22 2enhA14 LYS 20 H 0.08 -0.10 0.11 -0.55 8.42 7.96 2enhA14 LYS 20 HA -0.15 0.26 0.85 -0.75 4.32 4.52 2enhA14 LYS 20 HB2 -0.03 -0.01 -0.06 -0.04 1.87 1.74 2enhA14 LYS 20 HB3 -0.01 -0.09 -0.01 -0.04 1.79 1.64 2enhA14 LYS 20 HG2 -1.13 0.06 -0.11 -0.04 1.46 0.24 2enhA14 LYS 20 HG3 -0.31 0.06 0.06 -0.04 1.46 1.23 2enhA14 LYS 20 HD2 0.00 -0.01 -0.05 -0.04 1.69 1.59 2enhA14 LYS 20 HD3 -0.03 -0.03 -0.06 -0.04 1.68 1.52 2enhA14 LYS 20 HE2 0.03 -0.01 -0.02 -0.04 2.99 2.95 2enhA14 LYS 20 HE3 -0.14 0.01 -0.01 -0.04 2.99 2.81 2enhA14 ALA 21 H -0.34 0.20 0.18 -0.55 8.40 7.90 2enhA14 ALA 21 HA -0.03 0.25 0.93 -0.75 4.34 4.73 2enhA14 ALA 21 HB3 -0.08 0.02 0.05 -0.04 1.41 1.36 2enhA14 PHE 22 H 0.21 0.35 0.15 -0.55 8.34 8.50 2enhA14 PHE 22 HA -0.00 0.20 0.77 -0.75 4.62 4.83 2enhA14 PHE 22 HB2 -0.02 0.08 -0.11 -0.04 3.15 3.06 2enhA14 PHE 22 HB3 -0.03 -0.17 0.09 -0.04 3.06 2.90 2enhA14 PHE 22 HD2 -0.03 0.01 -0.21 -0.04 7.28 7.01 2enhA14 PHE 22 HE2 -0.15 0.01 -0.14 -0.04 7.38 7.05 2enhA14 PHE 22 HZ -0.79 -0.00 -0.12 -0.04 7.32 6.37 2enhA14 SER 23 H 0.19 0.05 0.14 -0.55 8.46 8.29 2enhA14 SER 23 HA 0.14 0.22 0.78 -0.75 4.49 4.87 2enhA14 SER 23 HB2 0.08 -0.12 0.18 -0.04 3.95 4.04 2enhA14 SER 23 HB3 0.07 0.04 0.04 -0.04 3.93 4.04 2enhA14 HIS 24 H 0.09 -0.00 0.13 -0.55 8.41 8.08 2enhA14 HIS 24 HA -0.17 0.31 0.81 -0.75 4.63 4.82 2enhA14 HIS 24 HB2 -0.05 0.08 0.06 -0.04 3.26 3.32 2enhA14 HIS 24 HB3 -0.16 -0.13 0.01 -0.04 3.20 2.87 2enhA14 HIS 24 HD2 -0.07 0.02 0.04 -0.04 6.97 6.91 2enhA14 HIS 24 HE1 0.11 0.08 0.05 -0.04 7.75 7.95 2enhA14 HIS 25 H -0.86 0.20 0.15 -0.55 8.41 7.35 2enhA14 HIS 25 HA -0.88 0.18 0.53 -0.75 4.63 3.70 2enhA14 HIS 25 HB2 -0.19 0.07 0.03 -0.04 3.26 3.13 2enhA14 HIS 25 HB3 -0.45 0.11 0.10 -0.04 3.20 2.92 2enhA14 HIS 25 HD2 -0.13 0.05 -0.08 -0.04 6.97 6.77 2enhA14 HIS 25 HE1 -0.15 0.07 0.05 -0.04 7.75 7.68 2enhA14 ALA 26 H -1.70 0.15 0.07 -0.55 8.40 6.37 2enhA14 ALA 26 HA -0.53 0.09 0.33 -0.75 4.34 3.48 2enhA14 ALA 26 HB3 -0.37 0.05 0.05 -0.04 1.41 1.10 2enhA14 SER 27 H -0.29 -0.02 -0.76 -0.55 8.46 6.84 2enhA14 SER 27 HA -0.17 0.10 0.34 -0.75 4.49 4.01 2enhA14 SER 27 HB2 -0.05 0.08 -0.02 -0.04 3.95 3.91 2enhA14 SER 27 HB3 -0.05 -0.06 0.02 -0.04 3.93 3.80 2enhA14 LEU 28 H -0.45 0.28 -0.08 -0.55 8.37 7.57 2enhA14 LEU 28 HA -0.97 0.05 0.40 -0.75 4.35 3.08 2enhA14 LEU 28 HB2 -0.33 -0.00 -0.03 -0.04 1.64 1.24 2enhA14 LEU 28 HB3 -0.19 0.06 0.15 -0.04 1.64 1.62 2enhA14 LEU 28 HG -0.01 0.04 -0.34 -0.04 1.64 1.28 2enhA14 LEU 28 HD13 0.05 -0.02 -0.10 -0.04 0.93 0.82 2enhA14 LEU 28 HD23 0.18 0.02 -0.07 -0.04 0.89 0.97 2enhA14 THR 29 H -0.22 0.64 -0.11 -0.55 8.28 8.04 2enhA14 THR 29 HA -0.04 0.05 0.35 -0.75 4.39 4.00 2enhA14 THR 29 HB -0.16 -0.05 -0.01 -0.04 4.32 4.06 2enhA14 THR 29 HG23 -0.04 0.01 -0.16 -0.04 1.22 0.99 2enhA14 GLN 30 H -0.16 0.65 -0.09 -0.55 8.47 8.33 2enhA14 GLN 30 HA -0.08 0.04 0.40 -0.75 4.36 3.97 2enhA14 GLN 30 HB2 -0.12 0.20 0.17 -0.04 2.15 2.36 2enhA14 GLN 30 HB3 -0.07 -0.02 -0.02 -0.04 2.02 1.87 2enhA14 GLN 30 HG2 -0.11 -0.05 0.06 -0.04 2.40 2.26 2enhA14 GLN 30 HG3 -0.07 -0.04 0.01 -0.04 2.39 2.24 2enhA14 GLN 30 HE21 -0.05 -0.00 0.01 -0.04 6.97 6.89 2enhA14 GLN 30 HE22 -0.04 0.01 0.02 -0.04 7.69 7.63 2enhA14 HIS 31 H -0.10 0.31 -0.46 -0.55 8.41 7.62 2enhA14 HIS 31 HA -0.10 0.03 0.43 -0.75 4.63 4.23 2enhA14 HIS 31 HB2 -0.17 -0.02 0.10 -0.04 3.26 3.13 2enhA14 HIS 31 HB3 -0.37 0.07 0.27 -0.04 3.20 3.13 2enhA14 HIS 31 HD2 0.05 0.01 -0.04 -0.04 6.97 6.95 2enhA14 HIS 31 HE1 0.13 0.03 -0.06 -0.04 7.75 7.80 2enhA14 GLN 32 H 0.02 0.61 -0.03 -0.55 8.47 8.53 2enhA14 GLN 32 HA -0.05 -0.10 0.31 -0.75 4.36 3.76 2enhA14 GLN 32 HB2 -0.00 0.21 0.08 -0.04 2.15 2.39 2enhA14 GLN 32 HB3 0.05 -0.03 -0.02 -0.04 2.02 1.97 2enhA14 GLN 32 HG2 0.21 -0.15 0.07 -0.04 2.40 2.49 2enhA14 GLN 32 HG3 0.08 0.30 0.09 -0.04 2.39 2.82 2enhA14 GLN 32 HE21 0.07 -0.03 -0.08 -0.04 6.97 6.89 2enhA14 GLN 32 HE22 0.06 0.00 -0.02 -0.04 7.69 7.69 2enhA14 ARG 33 H -0.12 0.18 -0.93 -0.55 8.46 7.03 2enhA14 ARG 33 HA -0.07 -0.04 0.30 -0.75 4.34 3.78 2enhA14 ARG 33 HB2 -0.11 0.08 0.14 -0.04 1.90 1.96 2enhA14 ARG 33 HB3 -0.07 -0.09 0.05 -0.04 1.80 1.64 2enhA14 ARG 33 HG2 -0.07 -0.01 0.07 -0.04 1.67 1.62 2enhA14 ARG 33 HG3 -0.07 -0.02 0.17 -0.04 1.67 1.71 2enhA14 ARG 33 HD2 -0.04 -0.06 0.03 -0.04 3.22 3.11 2enhA14 ARG 33 HD3 -0.04 0.00 0.04 -0.04 3.22 3.18 2enhA14 VAL 34 H -0.32 0.62 -0.13 -0.55 8.24 7.85 2enhA14 VAL 34 HA -0.16 -0.05 0.38 -0.75 4.13 3.54 2enhA14 VAL 34 HB -0.27 -0.07 0.03 -0.04 2.12 1.77 2enhA14 VAL 34 HG13 -0.22 -0.01 0.09 -0.04 0.97 0.79 2enhA14 VAL 34 HG23 -1.11 0.03 -0.07 -0.04 0.95 -0.25 2enhA14 HIS 35 H -0.49 0.21 -0.17 -0.55 8.41 7.42 2enhA14 HIS 35 HA -0.04 0.02 0.49 -0.75 4.63 4.35 2enhA14 HIS 35 HB2 -0.04 0.05 0.00 -0.04 3.26 3.24 2enhA14 HIS 35 HB3 -0.01 -0.05 0.08 -0.04 3.20 3.17 2enhA14 HIS 35 HD2 -0.01 -0.06 0.01 -0.04 6.97 6.87 2enhA14 HIS 35 HE1 0.07 0.02 -0.09 -0.04 7.75 7.71 2enhA14 SER 36 H 0.09 0.14 0.13 -0.55 8.46 8.28 2enhA14 SER 36 HA 0.02 0.17 0.87 -0.75 4.49 4.79 2enhA14 SER 36 HB2 0.01 0.11 -0.11 -0.04 3.95 3.92 2enhA14 SER 36 HB3 0.02 -0.03 -0.02 -0.04 3.93 3.86 2enhA14 GLY 37 H 0.01 0.16 0.11 -0.55 8.43 8.17 2enhA14 GLY 37 HA2 0.01 0.08 0.45 -0.51 4.01 4.05 2enhA14 GLY 37 HA3 0.01 -0.01 0.32 -0.51 4.01 3.83 2enhA14 GLU 38 H 0.01 0.07 0.00 -0.55 8.60 8.14 2enhA14 GLU 38 HA 0.00 0.20 0.93 -0.75 4.29 4.67 2enhA14 GLU 38 HB2 0.00 -0.03 0.05 -0.04 2.09 2.07 2enhA14 GLU 38 HB3 0.00 0.04 -0.05 -0.04 1.99 1.93 2enhA14 GLU 38 HG2 0.00 -0.04 -0.31 -0.04 2.34 1.96 2enhA14 GLU 38 HG3 0.00 -0.01 -0.05 -0.04 2.34 2.24 2enhA14 LYS 39 H 0.00 0.18 0.12 -0.55 8.42 8.18 2enhA14 LYS 39 HA 0.01 0.25 0.91 -0.75 4.32 4.73 2enhA14 LYS 39 HB2 0.01 0.06 -0.10 -0.04 1.87 1.80 2enhA14 LYS 39 HB3 0.00 -0.03 0.05 -0.04 1.79 1.77 2enhA14 LYS 39 HG2 0.00 -0.08 -0.55 -0.04 1.46 0.79 2enhA14 LYS 39 HG3 0.01 0.05 -0.09 -0.04 1.46 1.39 2enhA14 LYS 39 HD2 0.01 0.02 -0.07 -0.04 1.69 1.61 2enhA14 LYS 39 HD3 0.00 -0.02 -0.07 -0.04 1.68 1.55 2enhA14 LYS 39 HE2 0.00 0.05 -0.14 -0.04 2.99 2.87 2enhA14 LYS 39 HE3 0.00 0.01 -0.07 -0.04 2.99 2.89 2enhA14 PRO 40 HA 0.00 0.06 0.36 -0.51 4.44 4.35 2enhA14 PRO 40 HB2 0.00 0.01 0.10 -0.04 2.28 2.35 2enhA14 PRO 40 HB3 0.00 0.02 0.06 -0.04 2.02 2.06 2enhA14 PRO 40 HG2 0.00 0.03 0.11 -0.04 2.03 2.13 2enhA14 PRO 40 HG3 0.00 0.05 0.08 -0.04 2.03 2.12 2enhA14 PRO 40 HD2 0.00 0.11 0.17 -0.04 3.68 3.92 2enhA14 PRO 40 HD3 0.00 0.18 0.14 -0.04 3.65 3.93 2enhA14 SER 41 H 0.00 0.33 0.28 -0.55 8.46 8.52 2enhA14 SER 41 HA 0.00 0.08 0.42 -0.75 4.49 4.23 2enhA14 SER 41 HB2 0.00 -0.04 0.24 -0.04 3.95 4.11 2enhA14 SER 41 HB3 0.00 0.00 0.07 -0.04 3.93 3.96 2enhA14 GLY 42 H 0.00 0.39 0.30 -0.55 8.43 8.58 2enhA14 GLY 42 HA2 0.00 0.17 0.75 -0.51 4.01 4.42 2enhA14 GLY 42 HA3 0.00 -0.02 0.20 -0.51 4.01 3.68 2enhA14 PRO 43 HA 0.00 0.14 0.48 -0.51 4.44 4.56 2enhA14 PRO 43 HB2 0.00 0.04 -0.00 -0.04 2.28 2.27 2enhA14 PRO 43 HB3 0.00 0.04 0.11 -0.04 2.02 2.13 2enhA14 PRO 43 HG2 0.00 -0.00 0.10 -0.04 2.03 2.09 2enhA14 PRO 43 HG3 0.00 0.06 0.09 -0.04 2.03 2.14 2enhA14 PRO 43 HD2 0.00 0.10 0.21 -0.04 3.68 3.95 2enhA14 PRO 43 HD3 0.00 0.17 0.18 -0.04 3.65 3.97 2enhA14 SER 44 H 0.00 0.11 -0.15 -0.55 8.46 7.87 2enhA14 SER 44 HA 0.00 0.12 0.48 -0.75 4.49 4.34 2enhA14 SER 44 HB2 0.00 0.01 0.14 -0.04 3.95 4.06 2enhA14 SER 44 HB3 0.00 -0.03 0.09 -0.04 3.93 3.95 2enhA14 SER 45 H 0.00 0.60 -0.73 -0.55 8.46 7.78 2enhA14 SER 45 HA 0.00 0.05 0.81 -0.75 4.49 4.60 2enhA14 SER 45 HB2 0.00 -0.01 0.02 -0.04 3.95 3.92 2enhA14 SER 45 HB3 0.00 -0.03 -0.21 -0.04 3.93 3.65 2enhA14 GLY 46 H 0.00 0.10 0.02 -0.55 8.43 8.00 2enhA14 GLY 46 HA2 0.00 0.28 0.77 -0.51 4.01 4.55 2enhA14 GLY 46 HA3 0.00 0.03 0.15 -0.51 4.01 3.69