==== Secondary Structure Definition by the program DSSP, updated CMBI version by ElmK / April 1,2000 ==== DATE=8-MAY-2011 . REFERENCE W. KABSCH AND C.SANDER, BIOPOLYMERS 22 (1983) 2577-2637 . HEADER TRANSPORT 30-JUL-10 2XN6 . COMPND 2 MOLECULE: THYROXINE-BINDING GLOBULIN; . SOURCE 2 ORGANISM_SCIENTIFIC: HOMO SAPIENS; . AUTHOR X.QI,Y.YAN,Z.WEI,A.ZHOU . 371 2 0 0 0 TOTAL NUMBER OF RESIDUES, NUMBER OF CHAINS, NUMBER OF SS-BRIDGES(TOTAL,INTRACHAIN,INTERCHAIN) . 16442.0 ACCESSIBLE SURFACE OF PROTEIN (ANGSTROM**2) . 280 75.5 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(J) , SAME NUMBER PER 100 RESIDUES . 13 3.5 TOTAL NUMBER OF HYDROGEN BONDS IN PARALLEL BRIDGES, SAME NUMBER PER 100 RESIDUES . 108 29.1 TOTAL NUMBER OF HYDROGEN BONDS IN ANTIPARALLEL BRIDGES, SAME NUMBER PER 100 RESIDUES . 2 0.5 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I-5), SAME NUMBER PER 100 RESIDUES . 2 0.5 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I-4), SAME NUMBER PER 100 RESIDUES . 3 0.8 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I-3), SAME NUMBER PER 100 RESIDUES . 0 0.0 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I-2), SAME NUMBER PER 100 RESIDUES . 0 0.0 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I-1), SAME NUMBER PER 100 RESIDUES . 0 0.0 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+0), SAME NUMBER PER 100 RESIDUES . 0 0.0 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+1), SAME NUMBER PER 100 RESIDUES . 25 6.7 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+2), SAME NUMBER PER 100 RESIDUES . 28 7.5 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+3), SAME NUMBER PER 100 RESIDUES . 95 25.6 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+4), SAME NUMBER PER 100 RESIDUES . 5 1.3 TOTAL NUMBER OF HYDROGEN BONDS OF TYPE O(I)-->H-N(I+5), SAME NUMBER PER 100 RESIDUES . 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 *** HISTOGRAMS OF *** . 0 0 0 0 0 0 2 0 0 3 0 0 1 0 1 1 0 0 0 0 1 0 0 0 0 0 0 0 0 0 RESIDUES PER ALPHA HELIX . 1 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PARALLEL BRIDGES PER LADDER . 3 0 1 1 0 2 2 1 0 1 1 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ANTIPARALLEL BRIDGES PER LADDER . 0 0 0 0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 LADDERS PER SHEET . # RESIDUE AA STRUCTURE BP1 BP2 ACC N-H-->O O-->H-N N-H-->O O-->H-N TCO KAPPA ALPHA PHI PSI X-CA Y-CA Z-CA 1 19 A L > 0 0 167 0, 0.0 4,-0.5 0, 0.0 0, 0.0 0.000 360.0 360.0 360.0-147.4 -11.4 -6.5 9.8 2 20 A Y H > + 0 0 121 2,-0.2 4,-1.5 1,-0.2 5,-0.1 0.416 360.0 75.6 -98.1 -0.8 -11.1 -4.7 13.1 3 21 A K H > S+ 0 0 136 2,-0.2 4,-1.8 1,-0.2 -1,-0.2 0.915 99.6 46.3 -63.1 -46.6 -13.3 -1.9 12.0 4 22 A M H > S+ 0 0 19 1,-0.2 4,-2.9 2,-0.2 5,-0.2 0.843 107.1 57.4 -63.0 -38.5 -16.1 -4.3 12.5 5 23 A S H X S+ 0 0 16 -4,-0.5 4,-1.9 2,-0.2 -1,-0.2 0.882 106.6 48.1 -64.1 -40.8 -14.8 -5.4 15.9 6 24 A S H X S+ 0 0 21 -4,-1.5 4,-2.3 2,-0.2 242,-0.2 0.937 113.9 47.9 -62.7 -46.2 -14.9 -1.9 17.3 7 25 A I H X S+ 0 0 30 -4,-1.8 4,-2.1 1,-0.2 -2,-0.2 0.925 111.9 47.7 -62.8 -47.7 -18.5 -1.4 15.9 8 26 A N H X S+ 0 0 22 -4,-2.9 4,-2.0 1,-0.2 -1,-0.2 0.863 111.9 50.9 -62.4 -37.9 -19.8 -4.7 17.4 9 27 A A H X S+ 0 0 7 -4,-1.9 4,-2.3 -5,-0.2 -1,-0.2 0.909 109.5 49.9 -66.1 -42.4 -18.2 -4.0 20.8 10 28 A D H X S+ 0 0 47 -4,-2.3 4,-2.3 1,-0.2 -2,-0.2 0.881 109.2 52.2 -66.0 -34.6 -19.8 -0.5 20.9 11 29 A F H X S+ 0 0 5 -4,-2.1 4,-2.6 47,-0.2 5,-0.3 0.926 108.0 52.8 -61.2 -44.9 -23.2 -2.1 20.0 12 30 A A H X S+ 0 0 0 -4,-2.0 4,-2.4 1,-0.2 -2,-0.2 0.924 111.9 44.4 -56.7 -46.9 -22.6 -4.5 22.9 13 31 A F H X S+ 0 0 0 -4,-2.3 4,-2.2 2,-0.2 -1,-0.2 0.860 112.2 51.3 -70.0 -35.2 -22.0 -1.7 25.3 14 32 A N H X S+ 0 0 81 -4,-2.3 4,-1.6 2,-0.2 -2,-0.2 0.908 113.1 45.7 -68.0 -39.6 -24.9 0.4 24.1 15 33 A L H X S+ 0 0 0 -4,-2.6 4,-2.1 2,-0.2 -2,-0.2 0.911 109.9 55.2 -67.2 -41.2 -27.3 -2.5 24.5 16 34 A Y H X S+ 0 0 0 -4,-2.4 4,-2.0 -5,-0.3 -2,-0.2 0.923 106.6 51.0 -53.8 -47.7 -25.8 -3.2 27.9 17 35 A R H X S+ 0 0 59 -4,-2.2 4,-0.9 1,-0.2 -1,-0.2 0.868 106.3 54.3 -63.5 -34.5 -26.6 0.3 28.9 18 36 A R H >X S+ 0 0 85 -4,-1.6 4,-2.4 1,-0.2 3,-0.7 0.914 108.3 50.3 -62.3 -41.0 -30.2 -0.1 27.7 19 37 A F H 3X S+ 0 0 0 -4,-2.1 4,-3.0 1,-0.2 -2,-0.2 0.842 101.8 60.3 -66.0 -33.7 -30.4 -3.2 30.0 20 38 A T H 3< S+ 0 0 27 -4,-2.0 -1,-0.2 1,-0.2 5,-0.2 0.760 112.0 41.4 -65.7 -22.3 -29.1 -1.2 33.0 21 39 A V H << S+ 0 0 114 -4,-0.9 -2,-0.2 -3,-0.7 -1,-0.2 0.856 116.5 46.9 -85.1 -43.4 -32.1 1.1 32.5 22 40 A E H < S+ 0 0 80 -4,-2.4 -2,-0.2 1,-0.3 -3,-0.2 0.879 130.7 20.9 -66.3 -41.8 -34.6 -1.8 31.8 23 41 A T S >< S- 0 0 48 -4,-3.0 3,-1.0 -5,-0.1 -1,-0.3 -0.694 88.9-160.7-128.6 76.7 -33.5 -3.9 34.7 24 42 A P T 3 + 0 0 82 0, 0.0 -3,-0.1 0, 0.0 3,-0.1 -0.348 70.0 0.4 -68.5 136.9 -31.7 -1.5 37.1 25 43 A D T 3 S+ 0 0 131 -5,-0.2 2,-0.3 1,-0.2 -5,-0.1 0.851 106.6 117.7 52.3 42.2 -29.3 -2.9 39.8 26 44 A K S < S- 0 0 89 -3,-1.0 -1,-0.2 -6,-0.1 -3,-0.1 -0.925 75.6 -81.9-128.9 156.2 -29.9 -6.5 38.5 27 45 A N - 0 0 18 -2,-0.3 2,-0.4 341,-0.1 339,-0.2 -0.290 43.9-163.4 -50.9 138.2 -27.7 -9.2 37.0 28 46 A I E +A 365 0A 0 337,-2.3 337,-2.0 246,-0.1 2,-0.3 -0.991 17.1 161.3-124.9 135.7 -27.1 -8.7 33.3 29 47 A F E +A 364 0A 2 -2,-0.4 2,-0.3 335,-0.2 286,-0.2 -0.831 11.0 138.0-156.8 122.2 -25.8 -11.5 31.1 30 48 A F E -A 363 0A 0 333,-2.2 333,-2.5 -2,-0.3 3,-0.1 -0.968 48.5-115.6-153.0 164.1 -26.1 -11.7 27.3 31 49 A S > - 0 0 0 -2,-0.3 4,-1.8 331,-0.2 331,-0.2 -0.911 21.3-171.6-103.7 105.0 -24.2 -12.7 24.1 32 50 A P H > S+ 0 0 3 0, 0.0 4,-3.0 0, 0.0 5,-0.2 0.891 86.8 55.4 -63.0 -37.4 -23.8 -9.6 22.0 33 51 A V H > S+ 0 0 9 327,-0.9 4,-2.7 328,-0.3 5,-0.2 0.877 106.5 51.5 -64.0 -36.4 -22.4 -11.6 19.1 34 52 A S H > S+ 0 0 0 327,-0.4 4,-1.9 2,-0.2 -1,-0.2 0.921 113.0 44.1 -63.8 -44.5 -25.5 -13.9 19.1 35 53 A I H X S+ 0 0 0 -4,-1.8 4,-2.0 2,-0.2 -2,-0.2 0.948 117.1 45.6 -66.2 -48.1 -27.8 -10.8 19.0 36 54 A S H X S+ 0 0 2 -4,-3.0 4,-2.3 1,-0.2 -2,-0.2 0.900 112.3 51.4 -60.5 -44.8 -25.8 -9.1 16.3 37 55 A A H X S+ 0 0 0 -4,-2.7 4,-2.1 -5,-0.2 -1,-0.2 0.896 109.4 49.5 -62.3 -42.9 -25.4 -12.3 14.2 38 56 A A H X S+ 0 0 0 -4,-1.9 4,-2.0 2,-0.2 -1,-0.2 0.917 112.5 47.0 -62.9 -44.8 -29.2 -13.0 14.2 39 57 A L H X S+ 0 0 0 -4,-2.0 4,-2.1 2,-0.2 -2,-0.2 0.883 110.9 50.9 -67.7 -38.5 -30.1 -9.5 13.2 40 58 A V H X S+ 0 0 0 -4,-2.3 4,-1.3 2,-0.2 -1,-0.2 0.901 107.9 54.1 -68.0 -35.4 -27.5 -9.4 10.4 41 59 A M H >X S+ 0 0 0 -4,-2.1 3,-0.6 1,-0.2 4,-0.6 0.929 108.9 48.4 -58.9 -45.9 -28.9 -12.7 9.1 42 60 A L H >< S+ 0 0 8 -4,-2.0 3,-1.2 1,-0.2 4,-0.3 0.899 106.4 58.0 -60.2 -39.0 -32.3 -11.2 9.0 43 61 A S H >< S+ 0 0 0 -4,-2.1 3,-1.2 1,-0.3 -1,-0.2 0.760 90.3 71.3 -66.5 -24.5 -30.8 -8.2 7.1 44 62 A F H << S+ 0 0 36 -4,-1.3 -1,-0.3 -3,-0.6 -2,-0.2 0.828 104.8 40.8 -57.9 -33.2 -29.5 -10.5 4.3 45 63 A G T << S+ 0 0 0 -3,-1.2 254,-2.0 -4,-0.6 255,-0.7 0.392 102.6 93.3 -94.6 0.5 -33.1 -10.9 3.2 46 64 A A < - 0 0 3 -3,-1.2 2,-0.3 -4,-0.3 251,-0.3 -0.545 55.6-160.6 -94.3 159.4 -34.1 -7.3 3.7 47 65 A C >> - 0 0 37 249,-2.3 3,-1.2 -2,-0.2 4,-1.2 -0.926 46.9 -15.0-134.2 160.4 -34.1 -4.4 1.2 48 66 A C H 3> S- 0 0 91 -2,-0.3 4,-2.4 1,-0.2 3,-0.4 -0.101 126.1 -5.8 52.7-136.3 -34.0 -0.6 1.2 49 67 A S H 3> S+ 0 0 52 1,-0.2 4,-2.1 2,-0.2 -1,-0.2 0.781 132.9 60.1 -69.1 -25.9 -34.9 1.1 4.5 50 68 A T H <> S+ 0 0 1 -3,-1.2 4,-1.1 2,-0.2 -1,-0.2 0.940 112.4 39.6 -60.5 -45.7 -35.8 -2.2 6.2 51 69 A Q H X S+ 0 0 29 -4,-1.2 4,-1.9 -3,-0.4 5,-0.2 0.915 115.3 49.9 -69.7 -46.0 -32.2 -3.4 5.6 52 70 A T H X S+ 0 0 41 -4,-2.4 4,-2.5 1,-0.2 5,-0.2 0.890 107.1 55.2 -66.4 -36.9 -30.4 -0.1 6.3 53 71 A E H X S+ 0 0 28 -4,-2.1 4,-2.2 -5,-0.2 -1,-0.2 0.887 107.2 51.5 -60.7 -39.5 -32.2 0.4 9.6 54 72 A I H X S+ 0 0 1 -4,-1.1 4,-1.6 -5,-0.2 -2,-0.2 0.971 114.2 39.9 -64.8 -51.8 -31.1 -3.0 10.8 55 73 A V H <>S+ 0 0 0 -4,-1.9 5,-2.2 1,-0.2 4,-0.2 0.846 115.3 52.2 -71.9 -29.7 -27.4 -2.5 10.1 56 74 A E H ><5S+ 0 0 107 -4,-2.5 3,-1.2 -5,-0.2 -1,-0.2 0.897 107.8 52.2 -69.8 -37.3 -27.4 1.1 11.3 57 75 A T H 3<5S+ 0 0 17 -4,-2.2 -2,-0.2 1,-0.3 -1,-0.2 0.846 103.9 57.9 -62.3 -34.0 -29.0 -0.1 14.5 58 76 A L T 3<5S- 0 0 0 -4,-1.6 -1,-0.3 -5,-0.2 -47,-0.2 0.539 129.7 -99.4 -73.8 -8.2 -26.1 -2.6 14.8 59 77 A G T < 5S+ 0 0 43 -3,-1.2 -3,-0.2 1,-0.3 2,-0.2 0.352 75.6 138.1 114.0 -1.9 -23.8 0.4 14.7 60 78 A F < - 0 0 5 -5,-2.2 2,-0.6 4,-0.0 -1,-0.3 -0.508 43.5-148.6 -86.3 141.7 -22.6 0.5 11.1 61 79 A N > - 0 0 81 -2,-0.2 4,-2.9 1,-0.1 3,-0.3 -0.953 12.2-148.9-102.7 117.2 -22.2 3.6 8.9 62 80 A L T 4 S+ 0 0 43 -2,-0.6 5,-0.2 1,-0.2 -1,-0.1 0.634 95.5 57.1 -68.5 -15.0 -23.0 2.5 5.3 63 81 A T T 4 S+ 0 0 125 2,-0.1 -1,-0.2 3,-0.1 -3,-0.0 0.914 114.3 37.8 -73.5 -47.7 -20.5 5.1 3.9 64 82 A D T 4 S+ 0 0 114 -3,-0.3 -2,-0.2 1,-0.3 -1,-0.1 0.926 134.3 22.2 -67.7 -47.8 -17.6 3.7 5.9 65 83 A T S < S- 0 0 4 -4,-2.9 -1,-0.3 -62,-0.0 5,-0.1 -0.869 85.7-141.0-128.7 95.7 -18.7 0.0 5.5 66 84 A P >> - 0 0 64 0, 0.0 4,-2.1 0, 0.0 3,-0.9 -0.103 29.9-103.8 -53.9 153.0 -20.9 -0.7 2.5 67 85 A M H 3> S+ 0 0 29 1,-0.3 4,-2.4 2,-0.2 5,-0.1 0.859 122.2 52.1 -47.5 -45.3 -23.8 -3.2 2.9 68 86 A V H 3> S+ 0 0 87 1,-0.2 4,-2.6 2,-0.2 -1,-0.3 0.841 107.9 51.1 -64.4 -35.2 -21.8 -5.8 1.0 69 87 A E H <> S+ 0 0 93 -3,-0.9 4,-3.0 2,-0.2 -1,-0.2 0.884 109.8 50.2 -67.4 -39.6 -18.7 -5.4 3.2 70 88 A I H X S+ 0 0 0 -4,-2.1 4,-2.4 2,-0.2 5,-0.2 0.942 111.4 48.6 -61.9 -48.0 -20.8 -5.8 6.4 71 89 A Q H X S+ 0 0 42 -4,-2.4 4,-1.9 -5,-0.2 -2,-0.2 0.949 114.2 46.5 -56.4 -50.4 -22.4 -8.9 4.9 72 90 A H H X S+ 0 0 122 -4,-2.6 4,-2.3 1,-0.2 -2,-0.2 0.897 110.6 52.5 -55.1 -48.9 -18.9 -10.2 4.1 73 91 A G H X S+ 0 0 15 -4,-3.0 4,-2.3 1,-0.2 -1,-0.2 0.904 110.2 46.8 -58.1 -45.0 -17.4 -9.3 7.5 74 92 A F H X S+ 0 0 1 -4,-2.4 4,-2.0 2,-0.2 -1,-0.2 0.842 110.4 52.8 -71.0 -33.8 -20.2 -11.2 9.4 75 93 A Q H X S+ 0 0 36 -4,-1.9 4,-1.8 -5,-0.2 -1,-0.2 0.917 112.2 45.9 -63.9 -41.7 -19.8 -14.2 7.2 76 94 A H H X S+ 0 0 133 -4,-2.3 4,-2.4 2,-0.2 -2,-0.2 0.852 109.7 55.5 -68.1 -37.3 -16.0 -14.2 7.9 77 95 A L H X S+ 0 0 15 -4,-2.3 4,-2.6 2,-0.2 5,-0.2 0.945 108.4 46.3 -58.8 -51.4 -16.6 -13.7 11.7 78 96 A I H X S+ 0 0 3 -4,-2.0 4,-1.8 1,-0.2 14,-0.2 0.921 112.7 51.1 -62.1 -42.8 -18.9 -16.8 12.0 79 97 A C H X S+ 0 0 82 -4,-1.8 4,-0.7 1,-0.2 -1,-0.2 0.926 112.2 46.0 -57.7 -47.7 -16.4 -18.9 10.0 80 98 A S H >< S+ 0 0 28 -4,-2.4 3,-0.8 1,-0.2 -2,-0.2 0.906 109.7 53.0 -65.7 -43.8 -13.5 -17.8 12.2 81 99 A L H 3< S+ 0 0 1 -4,-2.6 -1,-0.2 1,-0.2 -2,-0.2 0.870 112.4 46.2 -60.6 -36.0 -15.3 -18.4 15.5 82 100 A N H 3< S+ 0 0 16 -4,-1.8 -1,-0.2 -5,-0.2 -2,-0.2 0.565 81.3 117.5 -83.7 -10.0 -16.2 -21.9 14.5 83 101 A F S << S- 0 0 145 -3,-0.8 -3,-0.0 -4,-0.7 2,-0.0 -0.420 80.3-100.5 -62.9 129.1 -12.7 -22.9 13.2 84 102 A P - 0 0 105 0, 0.0 2,-0.4 0, 0.0 -1,-0.1 -0.272 43.8-177.7 -61.4 128.8 -11.6 -25.7 15.4 85 103 A K B > -J 88 0B 42 3,-0.6 3,-1.7 5,-0.1 5,-0.1 -0.998 31.3-112.0-127.0 128.2 -9.2 -24.7 18.2 86 104 A K T 3 S+ 0 0 182 -2,-0.4 3,-0.1 1,-0.2 0, 0.0 -0.295 99.7 11.2 -60.4 138.4 -7.6 -27.3 20.6 87 105 A E T 3 S+ 0 0 120 1,-0.1 84,-0.6 83,-0.0 2,-0.5 0.393 110.2 96.5 73.0 0.4 -8.8 -27.0 24.2 88 106 A L E < -JK 85 170B 17 -3,-1.7 2,-0.6 82,-0.1 -3,-0.6 -0.984 55.5-161.3-121.8 125.4 -11.6 -24.6 23.3 89 107 A E E + K 0 169B 89 80,-2.6 80,-2.5 -2,-0.5 2,-0.3 -0.936 29.5 152.1 -96.9 116.0 -15.3 -25.5 22.6 90 108 A L E + K 0 168B 10 -2,-0.6 2,-0.4 78,-0.2 78,-0.2 -0.881 9.6 164.8-146.8 114.2 -16.9 -22.6 20.7 91 109 A Q E + K 0 167B 82 76,-2.3 76,-2.5 -2,-0.3 2,-0.4 -0.998 7.5 176.3-130.7 137.5 -19.8 -23.0 18.3 92 110 A I E + K 0 166B 0 -2,-0.4 2,-0.3 74,-0.2 74,-0.2 -0.996 20.0 146.1-136.3 127.8 -22.1 -20.4 16.9 93 111 A G E - K 0 165B 0 72,-2.1 72,-2.5 -2,-0.4 2,-0.3 -0.927 32.5-127.5-154.0 176.6 -24.7 -21.3 14.3 94 112 A N E -lK 118 164B 0 23,-2.8 25,-2.1 -2,-0.3 2,-0.4 -0.927 7.7-160.3-133.3 154.2 -28.2 -20.5 13.1 95 113 A A E -lK 119 163B 0 68,-2.6 68,-2.8 -2,-0.3 2,-0.5 -0.999 6.1-156.8-135.5 135.6 -31.4 -22.3 12.3 96 114 A L E -lK 120 162B 0 23,-2.8 25,-3.1 -2,-0.4 2,-0.8 -0.962 1.9-164.7-113.4 117.7 -34.2 -21.1 10.1 97 115 A F E -lK 121 161B 1 64,-3.2 64,-2.2 -2,-0.5 2,-0.5 -0.895 18.1-168.9-102.2 103.2 -37.7 -22.7 10.8 98 116 A I E -lK 122 160B 10 23,-2.2 25,-3.0 -2,-0.8 62,-0.2 -0.824 25.4-111.6-105.5 129.2 -39.6 -21.8 7.7 99 117 A G E > -l 123 0B 9 60,-2.5 3,-1.6 -2,-0.5 25,-0.2 -0.261 27.9-123.1 -53.8 138.1 -43.4 -22.2 7.4 100 118 A K T 3 S+ 0 0 115 23,-1.6 -1,-0.1 1,-0.3 24,-0.1 0.622 109.0 49.5 -66.2 -12.7 -44.2 -25.0 4.9 101 119 A H T 3 S+ 0 0 159 58,-0.1 -1,-0.3 2,-0.0 -2,-0.1 0.452 86.2 105.7-104.0 -2.8 -46.4 -22.6 2.8 102 120 A L < - 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