# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d"
;hsqct1etf3gpsi3d
;avance-version (07/04/04)
;3D H-1/X correlation via double inept transfer
;   using sensitivity improvement
;for measuring N-15 T1 relaxation times
;phase sensitive using Echo/Antiecho-TPPI gradient selection
;with decoupling during acquisition
;using f3 - channel
;using flip-back pulse
;as pseudo3D
;(use parameterset HSQCT1ETF3GPSI3D)
;
;$CLASS=HighRes
;$DIM=3D
;$TYPE=
;$SUBTYPE=
;$COMMENT=


prosol relations=<triple>


# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Avance.incl" 1
;Avance2.incl
;   for 1
;
;avance-version (07/08/21)
;
;$CLASS=HighRes Incl
;$COMMENT=





































































































































;$Id: Avance2.incl,v 1.17.2.1 2007/09/14 16:17:35 ber Exp $
# 23 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d" 2

# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Grad.incl" 1
;Grad2.incl  -  include file for Gradient Spectroscopy
;   for 1
;
;avance-version (07/01/17)
;
;$CLASS=HighRes Incl
;$COMMENT=



















define list<gradient> EA=<EA>



;$Id: Grad2.incl,v 1.12 2007/01/22 14:22:35 ber Exp $
# 24 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d" 2

# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Delay.incl" 1
;Delay.incl  -  include file for commonly used delays
;
;version 00/02/07
;
;$CLASS=HighRes Incl
;$COMMENT=


;general delays

define delay DELTA
define delay DELTA1
define delay DELTA2
define delay DELTA3
define delay DELTA4
define delay DELTA5
define delay DELTA6
define delay DELTA7
define delay DELTA8

define delay TAU
define delay TAU1
define delay TAU2
define delay TAU3
define delay TAU4
define delay TAU5


;delays for centering pulses

define delay CEN_HN1
define delay CEN_HN2
define delay CEN_HN3
define delay CEN_HC1
define delay CEN_HC2
define delay CEN_HC3
define delay CEN_HC4
define delay CEN_HP1
define delay CEN_HP2
define delay CEN_CN1
define delay CEN_CN2
define delay CEN_CN3
define delay CEN_CN4
define delay CEN_CP1
define delay CEN_CP2


;loop counters

define loopcounter COUNTER
define loopcounter SCALEF
define loopcounter FACTOR1
define loopcounter FACTOR2
define loopcounter FACTOR3



;$Id: Delay.incl,v 1.12 2005/11/10 12:16:58 ber Exp $
# 25 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d" 2



"p2=p1*2"
"p22=p21*2"
"d11=30m"
"d24=1s/(cnst4*cnst11)"
"d25=1s/(cnst4*cnst12)"
"d26=1s/(cnst4*4)"


"d10=3u"

"in10=inf2/2"

"DELTA2=p16+d16+8u"
"DELTA3=d25-p16-d16-4u"


"DELTA1=d25-p16-d16-larger(p2,p8)-d10*2"





"spoff1=0"
"spoff13=bf2*((cnst21+cnst22)/2000000)-o2"


aqseq 312


# 1 "mc_line 57 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d expanding definition part of mc command before ze"
; dimension 3 aq-mode (F2) QF (F1) Echo-Antiecho  F2->F1
define delay MCWRK
define delay MCREST
define loopcounter ST1CNT
"ST1CNT = td2 / (2)"
"MCWRK = d1"
"MCREST = d1 - d1"
    dccorr
# 57 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d"
1 ze
# 1 "mc_line 57 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d expanding definition of mc command after ze"
# 58 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d"
  d11 pl16:f3 st0
2 6m do:f3
3 3m
# 1 "mc_line 61 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d expanding start label for mc command"
4 MCWRK
  MCREST
# 62 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d"

  "TAU=vd-p26*2-p16-d16-8u"

  (p1 ph1)
  d26 pl3:f3
  (center (p2 ph1) (p22 ph1):f3 )
  d26 setnmr3|0 setnmr0|34|32|33 ctrlgrad 0
  (p1 ph2)

  4u pl0:f1
  (p11:sp1 ph1:r):f1
  4u
  p16:gp1
  d16 pl1:f1

  (p21 ph3):f3
  d25 
  (center (p2 ph1) (p22 ph1):f3  )
  d25 pl19:f1
  (p21 ph2):f3

  (p26 ph2):f1

  TAU cpds1:f1 ph1

  4u do:f1
  (p26 ph7):f1
  4u
  p16:gp4
  d16 pl1:f1

  (p21 ph8):f3
  4u
  p16:gp2*-1*EA
  d16
  DELTA3
  (p22 ph6):f3
  d10


  (center (p2 ph9) (p8:sp13 ph1):f2  )




  d10
  p16:gp2*EA
  d16
  DELTA1

  (center (p1 ph1) (p21 ph4):f3 )
  d24
  (center (p2 ph1) (p22 ph1):f3 )
  d24
  (center (p1 ph2) (p21 ph5):f3 )
  d26
  (center (p2 ph1) (p22 ph1):f3 )
  d26
  (p1 ph1)
  DELTA2
  (p2 ph1)
  4u
  p16:gp3
  d16 pl16:f3
  4u  setnmr3^0 setnmr0^34^32^33 ctrlgrad 7
  goscnp ph31 cpd3:f3

  3m do:f3
  3m st ivd
  lo to 3 times nbl

  3m ipp3 ipp4 ipp5 ipp8 ipp9 ipp31
  lo to 4 times ns

# 1 "mc_line 136 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d expanding mc command in line"
  MCWRK  wr #0 if #0 zd
  MCWRK
# 139 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct1etf3gpsi3d"
exit
   

ph0=0 
ph1=0 
ph2=1
ph3=0 0 0 0 2 2 2 2 
ph4=0 0 2 2
ph5=3 3 1 1
ph6=0
ph7=3
ph8=1 3
ph9=0 0 2 2
ph31=0 2 2 0 2 0 0 2
  

;pl0 : 120dB
;pl1 : f1 channel - power level for pulse (default)
;pl3 : f3 channel - power level for pulse (default)
;pl16: f3 channel - power level for CPD/BB decoupling
;pl19: f1 channel - power level for CPD/BB decoupling
;sp1 : f1 channel - shaped pulse  90 degree
;sp13: f2 channel - shaped pulse 180 degree  (Ca and C=O, adiabatic)
;p1 : f1 channel -  90 degree high power pulse
;p2 : f1 channel - 180 degree high power pulse
;p8 : f2 channel - 180 degree shaped pulse for inversion (adiabatic)
;p11: f1 channel -  90 degree shaped pulse
;p16: homospoil/gradient pulse
;p21: f3 channel -  90 degree high power pulse
;p22: f3 channel - 180 degree high power pulse
;p26: f1 channel -  90 degree pulse at pl19
;d1 : relaxation delay; 1-5 * T1
;d10: incremented delay                              [3 usec]
;d11: delay for disk I/O                             [30 msec]
;d16: delay for homospoil/gradient recovery
;d24: 1/(4J)YH for YH
;     1/(8J)YH for all multiplicities
;d25: 1/(4J)YH for YH
;     1/(8J)YH for all multiplicities
;d26: 1/(4J(YH))
;vd : variable delay, taken from vd-list
;cnst4: = J(YH)
;cnst11: for multiplicity selection = 4 for NH, 8 for all multiplicities
;cnst12: for multiplicity selection = 4 for NH, 8 for all multiplicities
;cnst21: CO chemical shift (offset, in ppm)
;cnst22: Calpha chemical shift (offset, in ppm)
;inf2: 1/SW(X) = 2 * DW(X)
;in10: 1/(2 * SW(X)) = DW(X)
;nd10: 2
;NS: 8 * n
;DS: >= 16
;td1: number of delays in vd-list
;td2: number of experiments in F2
;NBL: = td1
;FnMODE: QF in F1
;FnMODE: echo-antiecho in F2
;cpds1: decoupling according to sequence defined by cpdprg1
;cpd3: decoupling according to sequence defined by cpdprg3
;pcpd1: f1 channel - 90 degree pulse for decoupling sequence
;pcpd3: f3 channel - 90 degree pulse for decoupling sequence


;use gradient ratio:	gp 1 : gp 2 : gp 3 : gp 4
;                         50 :   80 : 16.2 :   30  for N-15

;for z-only gradients:
;gpz1: 50%
;gpz2: 80%
;gpz3: 16.2%
;gpz4: 30%

;use gradient files:   
;gpnam1: SINE.100
;gpnam2: SINE.100
;gpnam3: SINE.100
;gpnam4: SINE.100


                                          ;preprocessor-flags-start
;1: for C-13 and N-15 labeled samples start experiment with 
;             option -DLABEL_CN (eda: ZGOPTNS)
                                          ;preprocessor-flags-end



;$Id: hsqct1etf3gpsi3d,v 1.6.2.1 2007/12/14 16:06:46 ber Exp $